Doubly ionic hydrogen bond interactions within the choline chloride–urea deep eutectic solvent
نویسندگان
چکیده
منابع مشابه
Deep Eutectic Solvents with Dual Hydrogen Bond Donors
Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, 6 MALAYSIA 7 * Correspondence: [email protected]; Tel.: +60-53687623 8 9 10 Abstract: Deep eutectic solvents (DESs) are known as tunable solvents. It is possible to prepare 11 ternary deep eutectic solvent (TDES) are used for desired purpose by selecting the suitable molar 12 ratio and com...
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This study investigated the effect of water on the physical and electrochemical properties of a choline chloride deep eutectic solvent (DES). Physical and electrochemical measurements were performed on the DES containing varying amounts of water. When the water content was increased from 1% to 15 wt%, the viscosity and density declined while the conductivity increased significantly. Similarly, ...
متن کاملMicellization of alkyltrimethylammonium bromide surfactants in choline chloride:glycerol deep eutectic solvent.
Deep eutectic solvents have shown the ability to promote the self-assembly of surfactants in solution. However, some differences have been found compared with self-assembly in pure water and other polar organic solvents. The behaviour of alkyltrimethylammonium bromides in choline chloride:glycerol deep eutectic solvent has been studied by means of surface tension, X-ray and neutron reflectivity...
متن کاملSolvation dynamics of an ionic probe in choline chloride-based deep eutectic solvents.
Solvation of the thiocyanate ion in three different deep eutectic solvents (DES) was investigated by linear FTIR spectroscopy, and Two Dimensional IR spectroscopy. Linear infrared spectroscopy reveals that the thiocyanate ion forms a hydrogen bond through its sulphur atom, while its nitrile end remains free. Photon-echo vibrational spectroscopy shows that the thiocyanate has a frequency-frequen...
متن کاملCorrection: Molecular and ionic diffusion in aqueous - deep eutectic solvent mixtures: probing inter-molecular interactions using PFG NMR.
Correction for 'Molecular and ionic diffusion in aqueous - deep eutectic solvent mixtures: probing inter-molecular interactions using PFG NMR' by Carmine D'Agostino et al., Phys. Chem. Chem. Phys., 2015, 17, 15297-15304.
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2016
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c6cp02815b